Thermoresponsive self-assembled cyclodextrin-end-decorated PNIPAM for aqueous catalysis.
نویسندگان
چکیده
The catalytic performance of thermoresponsive poly(N-isopropylacrylamide) (PNIPAM) functionalized at the terminal position with randomly methylated β-cyclodextrin was demonstrated by the aqueous Rh-catalysed hydroformylation of higher olefins.
منابع مشابه
Supramolecular thermoresponsive hyperbranched polymers constructed from poly(N-isopropylacrylamide) containing one adamantyl and two β-cyclodextrin terminal moieties.
Poly(N-isopropylacrylamide) (PNIPAM) oligomer containing one adamantyl (AD) and two β-cyclodextrin (β-CD) moieties at the chain terminals, AD-PNIPAM-(β-CD)(2), was synthesized by atom transfer radical polymerization (ATRP) and successive click reactions. In aqueous solution, AD-PNIPAM-(β-CD)(2) spontaneously forms supramolecular thermoresponsive hyperbranched polymers via molecular recognition ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 12 شماره
صفحات -
تاریخ انتشار 2015